Journal article
S. Ferrara, Bo Wang, E. Haas, Karry Wright LeBlanc, J. Mague, J. P. Donahue
Inorganic chemistry, 2016
Inorganic chemistry, 2016
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APA
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Ferrara, S., Wang, B., Haas, E., LeBlanc, K. W., Mague, J., & Donahue, J. P. (2016). Synthesis and Structures of [LCu(I)(SSi(i)Pr3)] (L = triphos, carbene) and Related Compounds. Inorganic Chemistry.
Chicago/Turabian
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Ferrara, S., Bo Wang, E. Haas, Karry Wright LeBlanc, J. Mague, and J. P. Donahue. “Synthesis and Structures of [LCu(I)(SSi(i)Pr3)] (L = Triphos, Carbene) and Related Compounds.” Inorganic chemistry (2016).
MLA
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Ferrara, S., et al. “Synthesis and Structures of [LCu(I)(SSi(i)Pr3)] (L = Triphos, Carbene) and Related Compounds.” Inorganic Chemistry, 2016.
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@article{s2016a,
title = {Synthesis and Structures of [LCu(I)(SSi(i)Pr3)] (L = triphos, carbene) and Related Compounds.},
year = {2016},
journal = {Inorganic chemistry},
author = {Ferrara, S. and Wang, Bo and Haas, E. and LeBlanc, Karry Wright and Mague, J. and Donahue, J. P.}
}
Abstract
The mononuclear Cu(I) complexes [LCu(I)(SSi(i)Pr3)] (L = 1,1,1-tris(diphenylphosphinomethyl)ethane (triphos), 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes)) have been prepared by ligand displacement from [LCu(I)Cl] with (i)Pr3SiS(-). Both compounds are colorless, diamagnetic species and have been characterized structurally by X-ray crystallography. The compounds [(IMes)Cu(η(1)κ(S)-SC(O)CH3)] and [(triphos)Cu(η(1)κ(S)-SC(S)OCH3)] have been prepared in the context of synthesis aimed at [LCu(η(1)κ(S)-SCOS)] and [LCu(η(1)κ(S)-SCS2)] complexes, which are intended as synthons toward an analogue of the Mo(μ-OSCO)Cu intermediate proposed as occurring in the catalytic cycle of carbon monoxide dehydrogenase (CODH).
